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REE characteristics and metallogenic age of the Liuying fluorite deposit in Fangcheng, Henan Province |
LIU Ji-Feng( ), BAI De-Sheng( ), ZHANG Kai-Tao, WANG Jin-Lu, WEI Jian-Zheng, SU Yang-Yan |
No.2 Institute of Geological & Mineral Resources Survey of Henan,Zhengzhou 450001, China |
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Abstract In order to study the ore-forming material source and ore-forming age of the Liuying fluorite deposit, the authors tested and analyzed the REE of 11 samples of rocks and ores, and determined the mineralization age of fluorite by Sm-Nd method. The results show that the chondrite-normalized REE patterns of wall rocks (marble+mica quartz schist), fluorite ore and Niuxinshan biotite monzogranite all have a rightly-dipping trend, but the distribution curves and statistical values of different parameters of fluorite ore and biotite monzogranite are closer to each other, indicating that they have obvious genetic relationship.The metallogenic age of fluorite is 141 Ma and the values of εNd(t) are negative, which shows that the main metallogenic epoch is early Cretaceous and the crust source characteristics are obvious. The metallogenic age of fluorite ore is basically consistent with that of SHRIMP zircon U-Pb age of Niuxinshan biotite monzogranite (132.4~138.4 Ma), suggesting that there is a close relationship between them, and the material sources should be consistent or similar.
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Received: 18 September 2020
Published: 27 July 2021
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Corresponding Authors:
BAI De-Sheng
E-mail: 135236745@qq.com;baidh1968@163.com
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Regional geological map of the study area Q—Quaternary; Zh—Huanglianduo formation; Zd—Dongjia formation; Pt3m—Meiyaogou formation; Pt3n—Nannihu formation; Pt3s—Sanchuan formation; Pt3sn—Sanjiaotang formation; Pt3c—Cuizhuang formation; Pt2bd—Beidajian formation; Pt2b—Baicaoping formation; Pt2y—Yunmengshan formation; Pt2l—Longjiayuan formation; Pt2g—Gaoshanhe formation; Pt2m—Majiahe formation; 1—Qidingshan rock mass(K1Qηγ); 2—Niuxinshan rock mass(K1Nηγ); 3—Huangwan rock mass(T3Hβ); 4—Shuangshan biotitesyenite porphyry(Pt3SHξπ); 5—Shuangshan quartz syenite(Pt3SHξo); 6—Wangjiaying rock mass(Pt2Wξγ); 7—Geological boundary; 8—fault/supposed fault;9—anticline; 10—orebody; 11—research area
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Geological map of Liuying fluorite deposit 1—Quaternary; 2—dolomite quartz schist of Nannihu formation; 3—sericite quartz schist of Nannihu formation; 4—dolomite-marble of Nannihu formation; 5—banded marble of Nannihu formation ; 6—carbon phyllite rock and carbonaceous schist of Nannihu formation; 7—quartz rock of Gaoshanhe formation;8—orthoclase porphyry; 9—geological boundary; 10—fault and number; 11—fluorite ore body and number
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元素 | LY-H11 | LY-H13 | LY-H26 | LY-H20 | LY-H27 | D5 | LY-H15 | LY-H16 | LY-H17 | LY-H18 | LY-H14 | 岩性 | 萤石矿石 | 萤石矿石 | 萤石矿石 | 萤石矿石 | 萤石矿石 | 黑云母二 长花岗岩 | 大理岩 | 大理岩 | 大理岩 | 二云石英 片岩 | 二云石英 片岩 | La | 5.80 | 4.40 | 2.90 | 9.50 | 13.60 | 19.11 | 8.11 | 299.39 | 469.22 | 433.86 | 435.48 | Ce | 10.75 | 8.32 | 5.90 | 19.80 | 27.80 | 38.29 | 14.03 | 490.03 | 714.50 | 678.68 | 687.50 | Pr | 1.56 | 1.15 | 0.88 | 2.84 | 3.40 | 5.35 | 1.8 | 29.58 | 39.82 | 36.60 | 36.78 | Nd | 6.90 | 5.00 | 4.40 | 12.60 | 14.40 | 21.65 | 7.07 | 7.27 | 4.05 | 0.80 | 0.90 | Sm | 1.61 | 1.25 | 1.27 | 3.04 | 3.42 | 6.62 | 1.60 | 5.33 | 8.09 | 6.51 | 7.11 | Eu | 0.33 | 0.32 | 0.25 | 0.62 | 0.64 | 2.06 | 0.36 | 0.97 | 1.55 | 1.24 | 1.50 | Gd | 1.66 | 1.58 | 1.54 | 3.08 | 3.39 | 5.73 | 1.37 | 9.83 | 14.91 | 14.53 | 14.09 | Tb | 0.25 | 0.27 | 0.23 | 0.50 | 0.53 | 1.18 | 0.25 | 0.76 | 1.02 | 0.91 | 0.94 | Dy | 1.63 | 1.86 | 1.45 | 3.33 | 3.37 | 8.87 | 1.67 | 3.07 | 3.55 | 3.10 | 3.44 | Ho | 0.33 | 0.39 | 0.30 | 0.70 | 0.69 | 1.70 | 0.31 | 0.40 | 0.39 | 0.34 | 0.38 | Er | 0.92 | 1.11 | 0.81 | 2.06 | 1.99 | 5.11 | 0.96 | 1.52 | 1.66 | 1.47 | 1.52 | Tm | 0.13 | 0.15 | 0.11 | 0.31 | 0.29 | 0.82 | 0.17 | 0.16 | 0.14 | 0.13 | 0.12 | Yb | 0.75 | 0.92 | 0.61 | 1.92 | 1.90 | 5.00 | 1.16 | 1.01 | 0.91 | 0.82 | 0.76 | Lu | 0.11 | 0.14 | 0.09 | 0.29 | 0.29 | 0.75 | 0.2 | 0.14 | 0.13 | 0.11 | 0.10 |
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REE analysis results of various rocks and ores in the study area10-6
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参数 | LY-H11 | LY-H13 | LY-H26 | LY-H20 | LY-H27 | D5 | LY-H15 | LY-H16 | LY-H17 | LY-H18 | LY-H14 | | 岩性 | 萤石矿石 | 萤石矿石 | 萤石矿石 | 萤石矿石 | 萤石矿石 | 黑云母二 长花岗岩 | 大理岩 | 大理岩 | 大理岩 | 二云石英 片岩 | 二云石英 片岩 | | ΣREE | 32.73 | 26.86 | 20.74 | 60.59 | 75.71 | 122.23 | 39.07 | 849.45 | 1259.95 | 1179.08 | 1190.62 | | ΣLREE | 26.95 | 20.44 | 15.60 | 48.40 | 63.26 | 93.08 | 33.00 | 832.57 | 1237.23 | 1157.69 | 1169.25 | | ΣHREE | 5.78 | 6.42 | 5.14 | 12.19 | 12.45 | 29.15 | 6.07 | 16.88 | 22.72 | 21.39 | 21.37 | | ΣLREE/ΣHREE | 4.66 | 3.18 | 3.04 | 3.97 | 5.08 | 3.19 | 5.44 | 49.31 | 54.47 | 54.13 | 54.71 | | (La/Yb)N | 5.21 | 3.22 | 3.21 | 3.34 | 4.83 | 2.58 | 4.72 | 200.62 | 346.38 | 358.19 | 384.23 | | (La/Sm)N | 2.27 | 2.21 | 1.44 | 1.97 | 2.50 | 1.82 | 3.20 | 35.35 | 36.47 | 41.94 | 38.55 | | (Gd/Yb)N | 1.79 | 1.39 | 2.04 | 1.29 | 1.44 | 0.93 | 0.96 | 7.88 | 13.18 | 14.36 | 14.88 | | δEu | 0.61 | 0.70 | 0.55 | 0.61 | 0.57 | 1.00 | 0.74 | 0.40 | 0.43 | 0.38 | 0.45 | | δCe | 0.84 | 0.87 | 0.88 | 0.91 | 0.96 | 0.90 | 0.84 | 1.00 | 0.96 | 0.99 | 1.00 | |
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Rare earth element parameters of various rocks and ores in the study area10-6
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Normalized REE distribution pattern of magmatic rock, wall rock and ore
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样品编号 | 岩性 | 147Sm/144Nd | 143Nd/144Nd | T2DM | εNd(t) | 比值 | 2S | 比值 | 2S | LY-H11 | 块状紫色萤石 | 0.167673 | 0.000282 | 0.512405 | 0.000004 | 1229 | -3.67 | LY-H13 | 块状紫色萤石 | 0.148512 | 0.000250 | 0.512385 | 0.000003 | 1275 | -4.23 | LY-H20 | 块状紫色萤石 | 0.149577 | 0.000238 | 0.512390 | 0.000002 | 1260 | -4.06 | LY-H26 | 块状紫色萤石 | 0.123357 | 0.000196 | 0.512365 | 0.000004 | 1337 | -5.09 | LY-H27 | 块状紫色萤石 | 0.153880 | 0.0002554 | 0.512393 | 0.000003 | 1253 | -3.96 |
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Results of Sm-Nd isotopic analysis in the study area
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Sm-Nd isotopic isochron of fluorite in the study area
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