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Exploring the standards of Se-rich soil in Qinghai Province |
MA Qiang( ), ZHANG Ya-Feng, HUANG Qiang, JI Bing-Yan, Miao Guo-Wen, MA Feng-Juan, MA Ying |
The Fifth Geological Exploration Institute of Qinghai Province, Xining 810099,China |
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Abstract The acid-base properties and Se background values of the soil in Qinghai Province were obtained by analyzing the pH and Se content of the soil based on the data derived from the geochemical survey of land quality conducted in Qinghai Province. The Se enrichment models of root soil and crops such as wheat, rapeseed, pea, garlic, and forage were established accordingly. The recommended values of Se-rich soil in Qinghai were calculated by combining the recommended in take of Se in the population with the standard value of Se content in Se-rich agricultural and livestock products in Qinghai Province. It is recommended that the lower limit of Se-rich soil for alkaline soil and neutral and acidic soil in Qinghai Province should be 0.23×10-6 and 0.25×10-6, respectively. This study is greatly significant for the formulation of the local standards for Se-rich soil in Qinghai Province and for guiding the development of the selenium industry.
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Received: 16 May 2021
Published: 21 June 2022
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地区或单位 | 标准或文献 | 条件 | 硒含量值/10-6 | 中国地质调查局 | 天然富硒土地划定与标识(试行) DD2019—10 | pH≤7.5 pH>7.5 | ≥0.40 ≥0.30 | 黑龙江省 | 富硒土壤评价要求 DB23/T 2071—2018 | pH<6.5 6.5≤pH≤7.5 pH>7.5 | 0.4~3.0 0.35~3.0 0.325 | 河北省 | 天然富硒土地判定要求 | pH≤7.5 pH>7.5 | ≥0.40 ≥0.30 | 河南省 | 富硒土壤硒含量要求 DB41/T 1871—2019 | pH<6.5 6.5≤pH≤7.5 pH>7.5 | ≥0.35 ≥0.32 ≥0.3 | 宁夏回族自治区 | 宁夏富硒土壤标准 DB64/T 1220—2016 | 无 | ≥0.222 | 甘肃省 | 甘肃省富硒土壤标准研究与探讨 | pH>7.5 | ≥0.28 | 广西壮族自治区 | 土壤中全硒含量的分级要求 | 水田 旱地 园地 | 0.45~3.0 0.49~3.0 0.55~3.0 |
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Summary of different regions of standards for selenium-rich soils
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Spatial diagram of different scale workspaces in eastern Qinghai
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参数 | 酸性 pH<6.5 | 中性 6.5≤pH≤7.5 | 碱性 7.5<pH≤8.5 | 强碱性 pH>8.5 | 中位值 | 6.37 | 7.1 | 8.15 | 8.65 | 样品数 | 92 | 1175 | 5835 | 1171 | 占比 | 1% | 14% | 71% | 14% |
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pH distribution and statistics of the proportion of samples of soil
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The distribution of pH in soil
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类型 | 样品数 | 最小值/10-6 | 最大值/10-6 | 平均值/10-6 | 中位数/10-6 | 累频75%值/10-6 | 变异系数 | 背景值/10-6 | 特征值 | 8273 | 0.02 | 2.31 | 0.20 | 0.19 | 0.23 | 0.50 | 0.20 |
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Statistical table of characteristic values of soil Se content
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The distribution of Se in soil
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The distribution of mother-to-earth in eastern Qinghai
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指标 | 区间/10-6 | 平均值/10-6 | 百分比/% | 水溶态Se | 0.001~0.038 | 0.012 | 3.3 | 离子交换态Se | 0.001~0.036 | 0.011 | 3.1 | 碳酸盐态Se | 0.002~0.033 | 0.011 | 3.1 | 加和1) | 0.004~0.107 | 0.034 | 9.5 | 腐殖酸态Se | 0.011~0.159 | 0.052 | 14.3 | 强有机态Se | 0.012~0.775 | 0.143 | 31.8 | 残渣态Se | 0.055~0.627 | 0.172 | 43.0 | 加和2) | 0.078~1.561 | 0.367 | 89.1 | 铁锰氧化态Se | 0.001~0.016 | 0.005 | 1.5 | 全Se | 0.113~1.846 | 0.443 | 100 | pH | 7.99~9.06 | 8.56 | — |
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Statistical table of morphological eigenvalues of selenium species(n=50)
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Linear model of Se in wheat and root soil(n=161)
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Linear model of Se in rapeseed and root soil(n=173)
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Linear model of Se in pea and root soil(n=88)
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Linear model of Se in garlic and root soil(n=35)
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pH | 样本数 | 酸碱性 | pH | | 富集系数/% | 最大值 | 最小值 | 平均值 | 最大值 | 最小值 | 平均值 | pH≤7.5 | 7 | 中酸性 | 7.37 | 6.47 | 6.96 | | 73.3 | 25.4 | 53.6 | pH>7.5 | 16 | 碱性 | 8.85 | 7.78 | 8.24 | | 89.5 | 40.7 | 57.2 |
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Statistical table of Se in forage grass and root soil
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