武清凹陷浅层含氟地下水演化特点及成因分析

doi:10.11720/wtyht.2021.1084

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Abstract

In this paper, the Wuqing Sag, a fourth-level tectonic unit where the water source in the north of Wuqing is located, was selected as the research area, and 95 groundwater sampling points were set up. Fluoride groundwater in the first aquifer was taken as the study object.Based on hydrogeological survey and sample analysis, the authors investigated spatial distribution of F^- concentrations as well as evolution feature and genesis of fluoride groundwater in shallow aquifer from Wuqing Sag by means of hydrogeochemical plot, statistic analysis and geochemical modeling. The results show that the mass concentration of F^- in shallow groundwater in the study area is generally high, the distribution trend is that the concentration in the NW-SE direction is the highest, and the concentration gradually decreases toward both sides, that hydrogeochemical types of groundwater with high F^- concentration are relatively complex, and have the characteristics of weak alkali, high sodium and low calcium, and that the formation of high-fluorine water is mainly controlled by the strong evaporation and concentration, fluorite dissolution, calcite-dolomite precipitation, and F^- desorption in this area.

Key words： groundwater fluoride hydrogeochemistry special distribution evolution feature hydrochemical characteristics Wuqing Sag

Received: 22 February 2020 Published: 29 April 2021

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	Yue-Fang SHEN
	Han-Yu MA
	Yao-Dong YANG
	Yang CAO

Cite this article:

Yue-Fang SHEN,Han-Yu MA,Yao-Dong YANG, et al. Evolution characteristics and genesis of shallow fluorine-bearing groundwater in Wuqing Sag[J]. Geophysical and Geochemical Exploration, 2021, 45(2): 528-535.

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https://www.wutanyuhuatan.com/EN/10.11720/wtyht.2021.1084 OR https://www.wutanyuhuatan.com/EN/Y2021/V45/I2/528

Location of sampling sites and distribution of F^- concentration of groundwater in shallow aquifer in Wuqing Sag

指标	ρ(F^-)<1.0 mg·L^-1水样(N=56)			ρ(F^-)>1.0 mg·L^-1水样(N=39)
指标	最小值	最大值	平均值	最小值	最大值	平均值
pH	7.42	8.26	7.81	7.72	8.32	8.02
ρ(F^-)/(mg·L^-1)	0.28	1.0	0.64	1.04	3.92	1.89
ρ(K⁺)/(mg·L^-1)	0.3	31.2	3.1	0.4	2.2	1.0
ρ(Ca²⁺)/(mg·L^-1)	20.7	316.0	156.4	25.1	215.4	75.7
ρ(Na⁺)/(mg·L^-1)	38.3	530.3	192.7	46.4	610.3	273.9
ρ(Mg²⁺)/(mg·L^-1)	12.9	216.9	76.1	14.8	175.2	72.1
ρ(HC $O 3 -$ )/(mg·L^-1)	360.0	1031.2	567.2	299.0	1119.7	726.6
ρ(S $O 4 2 -$ )/(mg·L^-1)	0.30	500.70	194.7	9.4	828.3	156.5
ρ(Cl^-)/(mg·L^-1)	28.4	1045.8	299.3	42.5	744.4	235.6
TDS值/(mg·L^-1)	468.2	2600.7	1221.84	477	2825.75	1194.76

Descriptive statistics of chemical composition for groundwater samples from Wuqing Sag

Piper diagram of groundwater samples from Wuqing Sag

Relationship between F^- concentration and pH

Relationship between F^- concentration and TDS

Relationship between F^- and Ca²⁺ concentrations

SO42- concentrations
">

Relationship between F^- and $SO 4 2 -$ concentrations

Relationship between F^- and Cl^- concentrations

Gibbs plot

Relationship between ρ(F^-)and ρ(Na⁺)/[ρ(Na⁺)+ρ(Ca²⁺)]

Relationship of activities between F^- and Ca²⁺

Relationship between F^- concentration and saturation index of dolomine

Relationship between F^- concentration and saturation index of calcite

Relationship between F^- concentration and saturation index of fluorite

O3-)/[ρ(HC

O 3 -

)+ρ(Cl^-)]
">

Relationship between ρ(F^-) and ρ(HC $O 3 -$ )/[ρ(HC $O 3 -$ )+ρ(Cl^-)]

O3-)/[ρ(HC

O 3 -

)+ρ(S

O 4 2 -

)]
">

Relationship between ρ(F^-) and ρ(HC $O 3 -$ )/[ρ(HC $O 3 -$ )+ρ(S $O 4 2 -$ )]

[1]	国家质量监督检疫检验总局, 国家标准化管理委员会. GB/T14848—2017 地下水质量标准[S]. 北京: 标准出版社, 2017.
[1]	General Administration of Quality Supervision, Inspection and Quarantine,Standadization Administration. GB/T14848—2017 Standard for groundwater quality[S]. Beijing: Standards Press, 2017.
[2]	中华人民共和国卫生部, 国家标准化管理委员会. GB5749—2006 生活饮用水卫生标准[S]. 北京: 标准出版社, 2006.
[2]	Ministry of Health of the People's Republic of China,Standadization Administration. GB5749—2006 Standards for drinking water quality [S]. Beijing: Standards Press, 2017.
[3]	曾溅辉, 刘文生. 浅层高氟地下水元素的组分存在形式与地方性氟病之关系[J]. 水文地质工程地质, 1995,22(1):25-28.
[3]	Zeng J H, Liu W S. The mode of occurrence in shallow high fluorine groundwater and its relationship to endemic fluorosis[J]. Hydrogeology and Engineering Geology, 1995,22(1):25-28.
[4]	Gomez M L, Blarasin M T, Martnez D E. Arsenic and fluoride in a loess aquifer in the central area of Argentina[J]. Environmental Geology, 2009,57:143-155.
[5]	Arveti N, Sarma M R S, Aitkenhead J A, et al. Fluoride incidence in groundwater: A case study from Talupula, Andhra Pradesh[J]. India Environmental Monitoring and Assessment, 2011,172:427-443.
[6]	钱会, 马致远, 李培月. 水文地球化学[M]. 北京: 地质出版社, 2012.
[6]	Qian H, Ma Z Y, Li P Y. Hydrogeochemistry[M]. Beijing: Geological Publishing House, 2012.
[7]	汤洁, 卞建民, 李昭阳, 等. 松嫩平原氟中毒地区地下水氟分布规律和成因研究[J]. 中国地质, 2010,37(1):615-620.
[7]	Tang J, Bian J M, Li Z Y, et al. The distribution regularity and causes of luoride in groundwater of the fluorosis area, Songne Plain[J]. Geology in China, 2010,37(3):615-620.
[8]	Dhiman S D, Keshari K. Hydrogeochemical evaluation of high-fluoride ground waters:A case study from Mehsana District, Gujarat, India[J]. Hydrological Sciences. 2006,51(6):1149-1162.
[9]	Abida F, Harue M, Nousheen F. Toxic fluoride and arsenic contaminated groundwater in the Lahore and Kasur districts, Punjab, Pakistan and possible contaminant sources[J]. Environmental Pollution, 2006(7):1-11.
[10]	Robertson F N. Solubity controls of fluorine, barium and chromium in groundwater in alluvial basins of Arizona[J]. National Water Well Association, 1984: 96-102.
[11]	Gunnar J, Prosun B. Controls on the genesis of some high-fluoride groundwaters in India[J]. Applied Geochemistry, 2005(20):221-228.
[12]	曾溅辉, 刘文生, 彭玉荣. 浅层地下水氟的质量平衡反应模型及其化学演变[J]. 水文地质工程地质, 1995,22(5):12-16.
[12]	Zeng J H, Liu W S, Peng Y R. The mass balance reaction models for fluorine in shallow groundwater and its chemical evolution[J]. Hydrogeology and Engineering Geology, 1995,22(5):12-16.
[13]	许光泉, 刘进, 朱其顺, 等. 安徽淮北平原浅层地下水中氟的分布特征及影响因素分析[J]. 水资源与水工程学报, 2009,20(5):9-13.
[13]	Xu G Q, Liu J, Zhu Q S,etc.Analysis of distribution characteristics and influencing factors for the fluorine in the shallow groundwater in Huaibei Plain of Anhui[J]. Journal of Water Resources and Water Engineering, 2009,20(5):9-13.
[14]	李俊霞, 苏春利, 谢先军, 等. 多元统计方法在地下水环境研究中的应用——以山西大同盆地为例[J]. 地质科技情报, 2010,29(6):94-100.
[14]	Li J X, Su C L, Xie X J, et al. Application of multivariate statistical analysis to research the environment of groundwater:A case study at Datong Basin,Northern China[J]. Geological Science and Technology Information, 2010,29(6):94-100.
[15]	沈照理, 朱宛华, 钟佐燊. 水文地球化学基础[M]. 北京: 地质出版社, 1993.
[15]	Shen Z L, Zhu W H, Zhong Z S. Hydrogeochemical foundation[M]. Beijing: Geological Publishing House, 1993.
[16]	Gibbs R J. Mechanisms controlling world water chemistry[J]. Science, 1970,170:1088-1090.
[17]	Handa B K. Geochemistry and genesis of fluoride containing ground waters in India[J]. Ground Water, 1975,13(3):275-281.
[18]	毛若愚, 郭华明, 贾永锋, 等. 内蒙古河套盆地含氟地下水分布特点及成因[J]. 地学前缘, 2016,23(2):260-267.
[18]	Mao R Y, Guo H M, Jia Y F, et al. Distribution characteristics and genesis of fluoride groundwater in the Hetao basin, Inner Mongolia[J]. Earth Science Frontiers, 2016,23(2):260-268.
[19]	邢丽娜. 华北平原典型剖面上地下水化学特征和水文地球化学过程[D]. 北京:中国地质大学(北京), 2012.
[19]	Xing L N. Groundwater hydrochemical characteristics and hydrogeochemical processes approximately along flow paths in the North China Plain[D]. Beijing:China University of Geosciences(Beijing), 2012.
[20]	Karthikeyan M, Satheesh K K K, Elango K P. Conducting polymer/alumina composites as viable absorbents for the removal of fluoride ions from aqueous solution[J]. Journal of Fluorine Chemistry, 2009,130:894-901.
[21]	Su C M, Plus R W. Asrenate and arsenite removal by zerovalent iron: Effects of phosphate, and nitrate, relative to chloride[J]. Environmental Science and Technology, 2001,35(22):4562-4568.