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Assessing the distribution and ecological risks of heavy metals in surface sediments of the Maowei Sea estuary, Guangxi |
YAN Kun1,2( ), PANG Guo-Tao1, LI Wei1, MAO Fang-Song1 |
1. Yantai Geological Survey Center of Coastal Zone, China Geological Survey, Yantai 264000, China 2. School of Environmental Studies, China University of Geosciences(Wuhan), Wuhan 430000, China |
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Abstract A total of 13 surface sediment samples were collected from estuaries of the Maoling, Dalan, and Qinjiang rivers for heavy metal analysis, aiming to study the distribution characteristics and ecological risk of heavy metals in the surface sediments of the Maowei Sea estuary. The results are as follows. The average contents of heavy metals As, Cd, Cr, Cu, Hg, Pb, and Zn in Maowei Sea sediments were 7.78×10-6, 0.14×10-6, 37.6×10-6, 18.9×10-6, 0.0048×10-6, 22.5×10-6, and 54.7×10-6, respectively. They are all lower than the class-I standard specified in GB18668—2002. The heavy metals in the sediments show quite different spatial distribution, with high content of heavy metals concentrating in the industrial zone to the east of the Maowei Sea and near the Maoling River to the west of the Maowei Sea. The analysis of heavy metal pollution shows that most elements are at levels of no pollution to moderate pollution, and Cr is at a medium pollution level. As indicated by the ecological risk analysis, the heavy metals generally show potentially low potential risks, and Hg and Cd in the industrial zone to the east show moderate ecological risks. The sources of heavy metal pollutants were explored through correlation analysis, cluster analysis, and principal component analysis. The results show that heavy metal pollution is mainly controlled by rivers, and Hg, As and Cd are also affected by wastewater discharged from the port industrial zone. This comprehensive study shows that the Maowei Sea has a good ecological environment overall, but it is recommended to focus on the drainage of heavy metal pollution in the industrial zone to the west of the Maowei Sea.
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Received: 21 August 2021
Published: 17 August 2022
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Distribution of sampling stations
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参数 | As | Cd | Cr | Cu | Hg | Pb | Zn | 文献来源 | 最大值/10-6 | 19.8 | 0.45 | 74.3 | 31.7 | 0.12 | 46 | 123 | 本次工作 | 最小值/10-6 | 1.45 | 0.031 | 12.1 | 7.06 | 0.011 | 8.9 | 15.9 | 本次工作 | 平均值/10-6 | 7.78 | 0.14 | 37.6 | 18.9 | 0.048 | 22.5 | 54.7 | 本次工作 | 标准差/10-6 | 5.21 | 0.12 | 21.1 | 8.72 | 0.038 | 12.1 | 34.9 | 本次工作 | 变异系数 | 0.67 | 0.86 | 0.58 | 0.46 | 0.79 | 0.54 | 0.64 | 本次工作 | 国家一类标准/10-6 | 20 | 0.50 | 80.0 | 35.0 | 0.2 | 60.0 | 150 | GB 18668—2002 | 1984年所测含量/10-6 | 12.15 | 0.09 | | 17.2 | | 27.5 | 66.6 | 李树华[17] | 2010年所测含量/10-6 | 7.72 | 0.08 | | 12.72 | | 6.76 | 39.37 | 张丹等[4] | 2011年所测含量/10-6 | 13.52 | 0.16 | | 16.96 | 0.05 | 23.33 | 60.28 | 田海涛[3] | 2013年所测含量/10-6 | 8.3 | 0.08 | 12.3 | 11.3 | 0.05 | 8.6 | 69.1 | 舒俊林等[5] | 参考背景值/10-6 | 9.6 | 0.19 | 21.8 | 18.5 | 0.062 | 26.3 | 56.73 | 文献[18] |
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Contents of heavy metals in sediments of Maowei Sea Estuary
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Distribution of heavy metals in sediments of the estuaries
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Igeo值 | 级数 | 污染程度 | 比例/% | As | Cd | Cr | Cu | Hg | Pb | Zn | <0 | 0 | 无污染 | 84.7 | 84.7 | 53.8 | 76.9 | 76.9 | 92.3 | 76.9 | 0<I≤1 | 1 | 轻度污染 | 15.3 | 15.3 | 30.8 | 23.1 | 23.1 | 7.7 | 23.1 | 1<I≤2 | 2 | 偏中度污染 | 0 | 0 | 15.4 | 0 | 0 | 0 | 0 | 2<I≤3 | 3 | 中度污染 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | | 最大值 | 0.11 | 0.66 | 1.18 | 0.19 | 0.37 | 0.22 | 0.53 | Igeo | 最小值 | -3.31 | -3.20 | -1.43 | -1.97 | -3.22 | -2.15 | -2.42 | | 平均值 | -1.20 | -1.49 | -0.02 | -0.71 | -1.45 | -1.00 | -0.92 |
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Evaluation results of heavy metal accumulation index in sediments of Maowei Sea Estuary
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Distribution of potential ecological risk index of Er and ERI
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元素 | Mz | As | Cd | Cr | Cu | Hg | Pb | Zn | Mz | 1 | | | | | | | | As | 0.737** | 1 | | | | | | | Cd | 0.621* | 0.664* | 1 | | | | | | Cr | 0.731** | 0.856** | 0.738** | 1 | | | | | Cu | 0.567* | 0.689** | 0.671* | 0.897** | 1 | | | | Hg | 0.723** | 0.866** | 0.744** | 0.721** | 0.531 | 1 | | | Pb | 0.747** | 0.882** | 0.756** | 0.978** | 0.833** | 0.754** | 1 | | Zn | 0.692** | 0.802** | 0.787** | 0.985** | 0.908** | 0.667* | 0.972** | 1 |
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Correlation coefficients of heavy metal elements and median particle size in sediments of MaoWei Sea estuary
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Dual hierarchical clustering analysis
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Two-dimensional factor load of each heavy metal element
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