Nonnegative matrix factorization (NMF) is commonly used in hyperspectral image (HSI) unmixing due to its high interpretability and computability. To effectively address HSI noise and improve unmixing efficiency, this study proposed a method for hyperspectral unmixing based on spectral-spatial total variation nonnegative matrix factorization (SSTVNMF) with feature space augmentation. First, the original data space was converted to the feature space through feature extraction, allowing the unmixing process to be performed in the feature space for enhanced unmixing efficiency. Second, to reduce the impact of noise, the spatial information was extracted using the bilateral filtering (BF) method for enhanced feature extraction, thereby ensuring the accuracy of extracted features. Third, to ensure the effectiveness of the unmixing method, total variation (TV) regularization that considers both spatial and spectral features was established based on the NMF method. The spatial TV promotes abundance smoothing by calculating the horizontal and vertical differences in abundance between neighboring pixels. Based on the minimum-volume TV, the spectral TV enhances endmember extraction by applying constraint forces between endmembers to minimize the volume. Finally, the proposed method was verified using the synthetic data from the USGS spectral library as simulated data and the Jasper Ridge, APEX, and Cuprite datasets as actual data. The experimental results demonstrate that the proposed method outperformed other improved NMF-based methods in terms of qualitative and quantitative assessments.